Gamma-Tocotrienol → Tocotrienol

HRID 518122

Reaktionsgleichung

Reaktionsgleichung von HRID 518122
C[C:2]1[C:7]([OH:8])=[CH:6][C:5]2[CH2:9][CH2:10][C@:11]([CH2:14][CH2:15]/[CH:16]=[C:17](/[CH2:19][CH2:20]/[CH:21]=[C:22](/[CH2:24][CH2:25][CH:26]=[C:27]([CH3:29])[CH3:28])\[CH3:23])\[CH3:18])([CH3:13])[O:12][C:4]=2[C:3]=1C.CC1C2O[C@@](CC/C=C(/CC/C=C(/CCC=C(C)C)\C)\C)(C)CCC=2C=C(O)C=1>>[CH3:28][C:27]([CH3:29])=[CH:26][CH2:25][CH2:24]/[C:22](/[CH3:23])=[CH:21]/[CH2:20][CH2:19]/[C:17](/[CH3:18])=[CH:16]/[CH2:15][CH2:14][C:11]1([CH3:13])[O:12][C:4]2[CH:3]=[CH:2][C:7]([OH:8])=[CH:6][C:5]=2[CH2:9][CH2:10]1

Komponenten

3

Edukt 2

HCID 5282349Gamma-TocotrienolHCID 5282350Delta-Tocotrienol

Produkt 1

HCID 9929901Tocotrienol

Versuchsvorschrift

Both γ-tocotrienol, referred to herein as Compound 1, and δ-tocotrienol, referred to herein as Compound 2, were isolated from a tocotrienol-rich fraction of palm oil using normal phase vacuum liquid chromatography. Compounds 3-29 and 35-44 which are 3,4-dihydro-1,3-oxazines, Compounds 30-31 which are Mannich bases, and Compounds 32-34 which are hydroxymethyl tocotrienol analogs were prepared as semi synthetic derivatives of Compounds 1 and 2.

Quellen und Nachweise

ORD-Eintrag
ord-acdb35f1be1944a99c519740ecd14e79
Quelldatensatz
uspto-grants-2015_08
Patentnummer
US09115145B2

Verknüpfte Notizen

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