Potassium Carbonate → Ethyl 4-(benzyloxy)-3-hydroxybenzoate

HRID 521518Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 521518
[CH2:1]([O:3][C:4](=[O:23])[C:5]1[CH:10]=[CH:9][C:8]([O:11][CH2:12][C:13]2[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=2)=[C:7]([O:19]C(=O)C)[CH:6]=1)[CH3:2].C(=O)([O-])[O-].[K+].[K+]>CO>[CH2:1]([O:3][C:4](=[O:23])[C:5]1[CH:10]=[CH:9][C:8]([O:11][CH2:12][C:13]2[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=2)=[C:7]([OH:19])[CH:6]=1)[CH3:2]

Komponenten

4

Edukt 2

HCID 11430Potassium CarbonateHCID 67170201HCID 67170201, Verbindung

Produkt 1

HCID 11311797Ethyl 4-(benzyloxy)-3-hydroxybenzoate

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 887MethanolLösungsmittel

Versuchsvorschrift

The compound of step 1 (10 g, 31.8 mmol) was dissolved in methanol, potassium carbonate (88 mg, 0.636 mmol) was added and the mixture was stirred for 2 h under reflux. After evaporation to dryness, the residue was used without further purification in the subsequent step.

Aufarbeitung

  1. temperatureunder reflux
  2. customAfter evaporation to dryness
  3. customthe residue was used without further purification in the subsequent step

Quellen und Nachweise

ORD-Eintrag
ord-dfacff06dd0949c28dda9c235b25f569
Quelldatensatz
uspto-grants-2016_05
Patentnummer
US09328071B2

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