Sodium Hydroxide → Civetone

HRID 526660

Reaktionsgleichung

Reaktionsgleichung von HRID 526660
C(OC([CH:6]1[CH2:22][CH2:21][CH2:20][CH2:19][CH2:18][CH2:17][CH:16]=[CH:15][CH2:14][CH2:13][CH2:12][CH2:11][CH2:10][CH2:9][CH2:8][C:7]1=[O:23])=O)C.[OH-].[Na+]>CO>[CH2:20]1[CH2:21][CH2:22][CH2:6][C:7](=[O:23])[CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH:15]=[CH:16][CH2:17][CH2:18][CH2:19]1

Komponenten

4

Edukt 2

HCID 14798Sodium HydroxideHCID 53673108Ethyl 17-oxocycloheptadec-8-ene-1-carboxylate

Produkt 1

HCID 5315941Civetone

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 887MethanolLösungsmittel

Versuchsvorschrift

2-ethoxycarbonyl-9-cycloheptadecenone will be refluxed with about 10% NaOH in methanol for about 1 hour to give civetone. After completion of the reaction, the reaction mixture will be neutralized using about 10% sulfuric acid. The product will be extracted using ether and can be purified using silica-gel chromatography.

Quellen und Nachweise

ORD-Eintrag
ord-00fc4ff0450f49bc9168967cb6cbe090
Quelldatensatz
uspto-grants-2016_05
Patentnummer
US09346729B2

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