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HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
HRID 52683Erstellt: 23. Oktober 2026

Allyl chloride → (3-Chloropropyl)triethoxysilane

https://huagongshe.com/de/reaction/52683

Reaktionsgleichung

Beteiligte Stoffe

RolleNameHCIDEinwaage
EduktAllyl chlorideHCID 7850—
EduktTriethoxysilaneHCID 13830—
KatalysatorChloro(1,5-cyclooctadiene)iridium(I) dimerHCID 6436381—
LösungsmittelP-XyleneHCID 7809—
Produkt(3-Chloropropyl)triethoxysilaneHCID 7877161%

Reaktionsschritte

In analogy to Example 3, a homogeneous reaction solution of 4 g of p-xylene, 3.8 g (0.05 mol) of allyl chloride (instead of 4.2 g corresponding to 0.055 mol), 8.2 g (0.05 mol) of triethoxysilane and 0.16 mg (10-3 mol %) of chloro-(1,5-cyclooctadiene)iridium(I) dimer were reacted without a relatively long mixing or storage time. Analysis by gas chromatography gave a product yield of only 61% of 3-chloropropyltriethoxysilane.

Herkunft & Nachweise

DOI10.6084/m9.figshare.5104873.v1
PatentnummerUS05616762
Quelldatensatzuspto-grants-1997_04
ORD IDord-1046655f81d5414dad9edc05ddc70660
Quellennotizuspto-grants-1997_04