HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
Allyl chloride → (3-Chloropropyl)triethoxysilane
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | Allyl chloride | HCID 7850 | — |
| Edukt | Triethoxysilane | HCID 13830 | — |
| Katalysator | Chloro(1,5-cyclooctadiene)iridium(I) dimer | HCID 6436381 | — |
| Lösungsmittel | P-Xylene | HCID 7809 | — |
| Produkt | (3-Chloropropyl)triethoxysilane | HCID 78771 | 61% |
Reaktionsschritte
In analogy to Example 3, a homogeneous reaction solution of 4 g of p-xylene, 3.8 g (0.05 mol) of allyl chloride (instead of 4.2 g corresponding to 0.055 mol), 8.2 g (0.05 mol) of triethoxysilane and 0.16 mg (10-3 mol %) of chloro-(1,5-cyclooctadiene)iridium(I) dimer were reacted without a relatively long mixing or storage time. Analysis by gas chromatography gave a product yield of only 61% of 3-chloropropyltriethoxysilane.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US05616762 |
| Quelldatensatz | uspto-grants-1997_04 |
| ORD ID | ord-1046655f81d5414dad9edc05ddc70660 |
| Quellennotiz | uspto-grants-1997_04 |