tert-Butyl methylcarbamate → 1,1-Dimethylethyl (4-formyl-3-methylphenyl)methylcarbamate

HRID 534773Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 534773
Br[C:2]1[CH:9]=[CH:8][C:5]([CH:6]=[O:7])=[C:4]([CH3:10])[CH:3]=1.[CH3:11][NH:12][C:13](=[O:19])[O:14][C:15]([CH3:18])([CH3:17])[CH3:16]>>[CH:6]([C:5]1[CH:8]=[CH:9][C:2]([CH2:11][NH:12][C:13](=[O:19])[O:14][C:15]([CH3:18])([CH3:17])[CH3:16])=[CH:3][C:4]=1[CH3:10])=[O:7]

Komponenten

3

Edukt 2

HCID 527635tert-Butyl methylcarbamateHCID 135551504-Bromo-2-methylbenzaldehyde

Produkt 1

HCID 866181121,1-Dimethylethyl (4-formyl-3-methylphenyl)methylcarbamate

Versuchsvorschrift

The title compound was prepared from crude 4-bromo-2-methylbenzaldehyde (D91) and 1,1-dimethylethyl methylcarbamate (D83) using a method similar to that described for D84 in Description 84. δH (CDCl3, 400 MHz) 10.20 (1H, s), 7.76 (1H, d), 7.28 (1H, dd), 7.19 (1H, d), 3.31 (3H, s), 2.66 (3H, s), 1.49 (9H, s).

Quellen und Nachweise

ORD-Eintrag
ord-a4151cb120db4f1fb6a9f1696b683330
Quelldatensatz
uspto-grants-2014_10
Patentnummer
US08853218B2

Notizen zur Reaktion

Wird geladen…