2-Iodobenzylic alcohol → 2-Iodobenzaldehyde

HRID 537387

Reaktionsgleichung

Reaktionsgleichung von HRID 537387
[I:1][C:2]1[CH:9]=[CH:8][CH:7]=[CH:6][C:3]=1[CH2:4][OH:5]>ClCCl.[O-2].[Mn+2]>[I:1][C:2]1[CH:9]=[CH:8][CH:7]=[CH:6][C:3]=1[CH:4]=[O:5]

Komponenten

4

Edukt 1

HCID 1076292-Iodobenzylic alcohol

Produkt 1

HCID 6434392-IodobenzaldehydeAusbeute 91 %

Reagenzien, Katalysatoren, Lösungsmittel 2

HCID 160959Manganese oxideKatalysatorHCID 6344DichloromethaneLösungsmittel

Versuchsvorschrift

In a flask, 2-iodobenzyl alcohol (4 g, 17.09 mmol) was dissolved in dichloromethane (MC, 85 ml), and then, manganese oxide (MnO2, 14.86 g, 170.92 mmol) was added thereto. The obtained reaction product was stirred under the reflux condition. When the reaction was completed, the obtained reaction product was cooled to the room temperature, and then, fiteated and concentrated using celite, to obtain the title compound (3.6 g, yield 91%).

Aufarbeitung

  1. customThe obtained reaction product
  2. customthe obtained reaction product
  3. concentrationfiteated and concentrated

Quellen und Nachweise

ORD-Eintrag
ord-49e4f99a721a493cbbfd323ffbd7ab02
Quelldatensatz
uspto-grants-2014_10
Patentnummer
US08859817B2

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