Ammonia → 1,1-Cyclohexanedicarboxamide

HRID 538968

Reaktionsgleichung

Reaktionsgleichung von HRID 538968
C1(C(O)=O)(C(O)=O)CCCCC1.S(Cl)(Cl)=O.N.[C:18]1([C:27]([NH2:29])=[O:28])([C:24]([NH2:26])=[O:25])[CH2:23][CH2:22][CH2:21][CH2:20][CH2:19]1>>[C:18]1([C:27]([NH2:29])=[O:28])([C:24]([NH2:26])=[O:25])[CH2:19][CH2:20][CH2:21][CH2:22][CH2:23]1.[C:24]([C:18]1([C:27]#[N:29])[CH2:23][CH2:22][CH2:21][CH2:20][CH2:19]1)#[N:26]

Komponenten

6

Edukt 4

HCID 222AmmoniaHCID 24386Thionyl Chloride2×HCID 136906Cyclohexane-1,1-dicarboxylic acidHCID 2992041,1-Cyclohexanedicarboxamide

Produkt 2

HCID 2992041,1-CyclohexanedicarboxamideHCID 5445611,1-Cyclohexanedicarbonitrile

Versuchsvorschrift

Furthermore, as a method for producing bis(aminomethyl)cyclohexane, for example, Non-Patent Document 1 (Malachowski et al.) discloses the following: an acid chloride derivative is prepared using cyclohexanedicarboxylic acid with thionyl chloride; cyclohexane diamide is prepared using the acid chloride derivative with ammonia; and thereafter, the cyclohexane diamide is further allowed to react with thionyl chloride to obtain dicyanocyclohexane, and then the obtained dicyanocyclohexane is hydrogenated.

Aufarbeitung

  1. customis prepared

Quellen und Nachweise

ORD-Eintrag
ord-17d89f5f75154560a35f326706e8dd50
Quelldatensatz
uspto-grants-2014_10
Patentnummer
US08865938B2

Verknüpfte Notizen

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