HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
Iodoform → 1-Oxo-1-(4-chlorophenyl)-3-iodo-2-propene
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | Iodoform | HCID 6374 | — |
| Edukt | (4-Chlorophenyl)(oxo)acetaldehyde | HCID 269588 | — |
| Katalysator | chromium(II) dichloride | HCID 10197677 | — |
| Lösungsmittel | Tetrahydrofuran | HCID 8028 | — |
| Produkt | 1-Oxo-1-(4-chlorophenyl)-3-iodo-2-propene | HCID 54373096 | — |
Reaktionsschritte
This compound is prepared in a manner analogous to that of Step C of Example 4, using 6.7 grams (0.04 mole) of 4-chlorophenylglyoxal (prepared by the method of Kornblum et al., JACS, (1957), 79, 6562), 29.5 grams (0.24 mole) of anhydrous chromium(II) dichloride, and 31.5 grams (0.08 mole) of iodoform in 600 mL of tetrahydrofuran, yielding 1-oxo-1-(4-chlorophenyl)-3-iodo-2-propene.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US05622954 |
| Quelldatensatz | uspto-grants-1997_04 |
| ORD ID | ord-96efb8b9fa07495b9c0fddd1bf2d549f |
| Quellennotiz | uspto-grants-1997_04 |