4-Methoxyphenol → Urethane acrylate

Temperatur

40 °C

Into 50 parts of toluene, 5.8 parts of behenyl alcohol (“NAA-422”, trade name, produced by NOF Corporation, hydroxyl value: 180) was added and the mixture was heated up to 40° C. After thorough dissolution of the behenyl alcohol, 50 parts of hexamethylene diisocyanate subjected to isocyanurate modification (“TAKENATE D-170N”) was added and the mixture was maintained at 70° C. for 30 minutes. Subsequently, 0.02 parts of dibutyltin laurate was added and the mixture was maintained at 70° C. for 3 hours. Further, 2.8 parts of 2-hydroxyethyl acrylate (Light Ester HOA), 36.1 parts of polycaprolactone-modified hydroxyethyl acrylate (“PLACCEL FA1”), 48.1 parts of polycaprolactone-modified hydroxyethyl acrylate (“PLACCEL FA5”), 0.02 parts of dibutyltin laurate and 0.02 parts of hydroquinone monomethyl ether were added and the mixture was maintained at 70° C. for 5 hours. Thereafter, 92.8 parts of toluene was added to obtain a urethane acrylate having a solid content of 50% by weight. The average number of repetitions per one molecule of the urethane acrylate relative to the number of repetitions of a caprolactone unit per one residue of an acrylate monomer is 2. Further, the maximum difference in the number of repetitions between two kinds of the urethane acrylates is 5.

1. additionwas added
2. temperaturethe mixture was maintained at 70° C. for 30 minutes
3. temperaturethe mixture was maintained at 70° C. for 3 hours
4. temperaturethe mixture was maintained at 70° C. for 5 hours

ORD-Eintrag

ord-322ffd5ad37a4837bd6265a5574f150c

Quelldatensatz

uspto-grants-2011_05

DOI

10.6084/m9.figshare.5104873.v1

Patentnummer

US07939608B2