m-Chloroperbenzoic acid → HCID 178508075, Verbindung

HRID 555221

Reaktionsgleichung

Reaktionsgleichung von HRID 555221
[NH2:1][C:2]1[C:7]([N+:8]([O-:10])=[O:9])=[CH:6][CH:5]=[CH:4][N:3]=1.ClC1C=CC=C(C(OO)=[O:19])C=1>CC(C)=O>[NH2:1][C:2]1[C:7]([N+:8]([O-:10])=[O:9])=[CH:6][CH:5]=[CH:4][N+:3]=1[O-:19]

Komponenten

4

Edukt 2

HCID 70297m-Chloroperbenzoic acidHCID 778873-Nitropyridin-2-ylamine

Produkt 1

HCID 178508075HCID 178508075, Verbindung

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 180AcetoneLösungsmittel3×

Versuchsvorschrift

To a solution of 2-amino-3-nitropyridine (5.0 g; 36 mmol) in acetone (250 mL) was added a solution of m-chloroperbenzoic acid (7.5 g; 100 mmol) in acetone (50 mL). The shiny orange solution was stirred at room temperature for 3 days. The resulting precipitate was dissolved again under heating and the solution poured onto a silica gel column. Column chromatography using acetone as eluant gave the title compound as an orange solid.

Aufarbeitung

  1. dissolutionThe resulting precipitate was dissolved again
  2. temperatureunder heating
  3. additionthe solution poured onto a silica gel column

Quellen und Nachweise

ORD-Eintrag
ord-f7313a66e43d401fa561836b9a73d649
Quelldatensatz
uspto-grants-2011_11
Patentnummer
US08053212B1

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