Hydrochloric Acid → 3-Nitryloxy-2,2-bis(nitryloxymethyl)propionic acid hydrazide

HRID 567932Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 567932
[N+:1]([O:4][CH2:5][C:6]([CH2:16][O:17][N+:18]([O-:20])=[O:19])([CH2:11][O:12][N+:13]([O-:15])=[O:14])[C:7](OC)=[O:8])([O-:3])=[O:2].Cl.[NH2:22][NH2:23].Cl>>[N+:1]([O:4][CH2:5][C:6]([CH2:16][O:17][N+:18]([O-:20])=[O:19])([CH2:11][O:12][N+:13]([O-:15])=[O:14])[C:7]([NH:22][NH2:23])=[O:8])([O-:3])=[O:2]

Komponenten

4

Edukt 3

HCID 313Hydrochloric AcidHCID 115031Hydrazinium chlorideHCID 15380869Methyl 2,2-bis(nitryloxymethyl)-3-nitryloxypropionate

Produkt 1

HCID 153808743-Nitryloxy-2,2-bis(nitryloxymethyl)propionic acid hydrazideAusbeute 63 %

Versuchsvorschrift

1 g (3.5 mmol) of methyl 2,2-bis(nitryloxymethyl)-3-nitryloxypropionate is heated for 5 hours in a water bath with excess aqueous hydrazine hydrochloride solution. The mixture is poured onto ice and weakly acidified with hydrochloric acid. The oil which has deposited is separated by column chromatography to give 3-nitryloxy-2,2-bis(nitryloxymethyl)propionic acid hydrazide (Tri-PA hydrazide) as a colourless oil. Yield: 63%. Elemental analysis: (C: conforms, H: conforms, N: conforms).

Aufarbeitung

  1. additionThe mixture is poured onto ice
  2. customThe oil which has deposited is separated by column chromatography

Quellen und Nachweise

ORD-Eintrag
ord-907267379249417fb39aad15005fd53e
Quelldatensatz
uspto-grants-2001_01
Patentnummer
US06180664B2

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