Dichlorotetramethyldisilane → HCID 178448655, Verbindung

HRID 568932Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 568932
C([C:5]1[C:15]([Cl:16])=[CH:14][CH:13]=[C:7]2[C:8]([NH:10][C:11](=[O:12])[C:6]=12)=[O:9])CCC.Cl[Si](Cl)(C)[Si:19]([CH3:22])(C)[CH3:20]>CC1C=CC=CC=1C.C1C=CC([P]([Pd]([P](C2C=CC=CC=2)(C2C=CC=CC=2)C2C=CC=CC=2)([P](C2C=CC=CC=2)(C2C=CC=CC=2)C2C=CC=CC=2)[P](C2C=CC=CC=2)(C2C=CC=CC=2)C2C=CC=CC=2)(C2C=CC=CC=2)C2C=CC=CC=2)=CC=1>[CH2:15]([N:10]1[C:11](=[O:12])[C:6]2=[C:5]([SiH:19]([CH3:22])[CH3:20])[C:15]([Cl:16])=[CH:14][CH:13]=[C:7]2[C:8]1=[O:9])[CH2:5][CH2:6][CH3:7]

Komponenten

5

Edukt 2

HCID 170204DichlorotetramethyldisilaneHCID 70407054HCID 70407054, Verbindung

Produkt 1

HCID 178448655HCID 178448655, VerbindungAusbeute 24 %

Reagenzien, Katalysatoren, Lösungsmittel 2

HCID 178418397HCID 178418397, VerbindungKatalysatorHCID 7237O-XyleneLösungsmittel

Versuchsvorschrift

A reaction mixture containing 5 gm (0.021 moles) of n-butyl-4-chlorophthalimide and 3.95 gm (0.021 moles) of 1.2 dichlorotetramethyldisilane dissolved in 10 ml of o-xylene was heated to 150° C. in the presence of 5 mole % tetrakis(triphenylphosphine)palladium. After 24 hours reaction time, GC and GC/MS analysis showed a 24% yield of N-butyl-4-chlorodimethylsilyl-phthalimide. The product is readily isolatable by vacuum distillation.

Aufarbeitung

  1. customAfter 24 hours reaction time, GC and GC/MS analysis

Quellen und Nachweise

ORD-Eintrag
ord-013551d2b6d1497a9976f6934ce36958
Quelldatensatz
uspto-grants-1988_03
Patentnummer
US04730055

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