HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
Ethyl Bromide → N,N-Diethyl-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)aniline
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | Ethyl Bromide | HCID 6332 | — |
| Edukt | Tetrahydrofuran | HCID 8028 | — |
| Edukt | Sodium hydride | HCID 24758 | — |
| Edukt | 4-(Tetramethyl-1,3,2-dioxaborolan-2-yl)aniline | HCID 2734620 | — |
| Produkt | N,N-Diethyl-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)aniline | HCID 44629855 | — |
Reaktionsschritte
A mixture of 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzenamine (100 mg, 0.45 mmol) and bromoethane (200 mg, 1.8 mmol), NaH (100 mg, 1.8 mmol) in THF was stirred at room temperature overnight, and concentrated in vacuo to give the crude title compound used for the next step. MS (m/z): 276 (M+H)+.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US09434726B2 |
| Quelldatensatz | uspto-grants-2016_09 |
| ORD ID | ord-d87bad50eb66433bb162f6a1119d5ebd |
| Quellennotiz | uspto-grants-2016_09 |