6-Benzoylbenzoselenazolinone → Bis(2-amino-5-benzoylphenyl) diselenide

HRID 5920Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 5920
[C:1]([C:9]1[CH:18]=[CH:17][C:12]2[N:13]=C[Se:15](=O)[C:11]=2[CH:10]=1)(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1>[OH-].[Na+]>[NH2:13][C:12]1[CH:17]=[CH:18][C:9]([C:1](=[O:8])[C:2]2[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=2)=[CH:10][C:11]=1[Se:15][Se:15][C:11]1[CH:10]=[C:9]([C:1](=[O:8])[C:2]2[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=2)[CH:18]=[CH:17][C:12]=1[NH2:13]

Komponenten

3

Edukt 1

HCID 1317181726-Benzoylbenzoselenazolinone

Produkt 1

HCID 10370310Bis(2-amino-5-benzoylphenyl) diselenide

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 14798Sodium HydroxideLösungsmittel

Versuchsvorschrift

1.5 g (0.005 mol) of 6-benzoylbenzoselenazolinone are introduced together with 20 cm3 of 10% sodium hydroxide into a ground-necked flask. The mixture is heated to reflux with stirring for two hours. After cooling, the reaction medium is neutralized. The precipitate is drained, washed with water and dried and the product is recrystallized in toluene.

Aufarbeitung

  1. temperatureThe mixture is heated
  2. temperatureto reflux
  3. temperatureAfter cooling
  4. washwashed with water
  5. customdried
  6. customthe product is recrystallized in toluene

Quellen und Nachweise

ORD-Eintrag
ord-20f53bdf122d4c0eb79fea6119fe9f55
Quelldatensatz
uspto-grants-1993_09
Patentnummer
US05246951

Notizen zur Reaktion

Wird geladen…