Sulfanium bromide → Sulfonium perfluorobutane sulfonate

HRID 597756Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 597756
[Br-].[SH3+:2].[F:3][C:4]([F:19])([S:15]([O-:18])(=[O:17])=[O:16])[C:5]([F:14])([F:13])[C:6]([F:12])([F:11])[C:7]([F:10])([F:9])[F:8].[Na+]>[N+](C)([O-])=O>[F:19][C:4]([F:3])([S:15]([O-:18])(=[O:17])=[O:16])[C:5]([F:13])([F:14])[C:6]([F:12])([F:11])[C:7]([F:10])([F:9])[F:8].[SH3+:2]

Komponenten

4

Edukt 2

HCID 23498378Sulfanium bromideHCID 23678450Sodium perfluorobutanesulfonate

Produkt 1

HCID 22483813Sulfonium perfluorobutane sulfonate

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 6375NitromethaneLösungsmittel

Versuchsvorschrift

The thus obtained monomer precursor is mixed with, for example, phenacyl bromide in acetonitrile or nitromethan at room temperature, to thereby obtain the corresponding sulfonium bromide. With the thus obtained sulfonium bromide, for example, sodium perfluorobutane sulfonate is mixed in nitromethane at room temperature to thereby obtain the targeted product of sulfonium perfluorobutane sulfonate. Moreover, the thus obtained sulfonium perfluorobutanesulfonate can be further purified by recrystallization.

Quellen und Nachweise

ORD-Eintrag
ord-b7f149b3e99a4d5aabb5b4e532189636
Quelldatensatz
uspto-grants-2011_03
Patentnummer
US07897321B2

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