Potassium Hydroxide → O-2-trifluoromethylphenyl dimethylthiocarbamate

Reaktionsgleichung

[F:1][C:2]([F:11])([F:10])[C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][C:4]=1[OH:9].[OH-].[K+].[CH3:14][N:15]([CH3:19])[C:16](Cl)=[S:17]>>[CH3:14][N:15]([C:16]([O:9][C:4]1[C:3]([C:2]([F:10])([F:11])[F:1])=[CH:8][CH:7]=[CH:6][CH:5]=1)=[S:17])[CH3:19]

Komponenten

Edukt 3

HCID 14797Potassium Hydroxide

HCID 27871Dimethylthiocarbamoyl chloride

HCID 679582-Trifluoromethylphenol

Produkt 1

HCID 14795406O-2-trifluoromethylphenyl dimethylthiocarbamateAusbeute 89 %

Versuchsvorschrift

If the procedure described in Preparation XI is followed starting from 3.95 g (24.3.10-3 mol) of 2-tri-fluoromethylphenol, 1.43 g (25.6.10-3 mol) of potassium hydroxide and 3.46 g (28.10-3 mol) of dimethylthiocarbamoyl chloride, 5.37 g (yield: 89%) of a yellow oil are obtained.

Quellen und Nachweise

ORD-Eintrag: ord-be2199f40d44415e9d6c4b76de61d7c9
Quelldatensatz: uspto-grants-1993_09
DOI: 10.6084/m9.figshare.5104873.v1
Patentnummer: US05246961

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