Iodine → HCID 14914462, Verbindung

HRID 604602Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 604602
[C:1]([C:5]1[CH:10]=[CH:9][C:8]([O:11][CH3:12])=[CH:7][CH:6]=1)([CH3:4])([CH3:3])[CH3:2].[I:13]I>CO.S([O-])([O-])(=O)=O.[Ag+2]>[C:1]([C:5]1[CH:6]=[CH:7][C:8]([O:11][CH3:12])=[C:9]([I:13])[CH:10]=1)([CH3:4])([CH3:2])[CH3:3]

Komponenten

5

Edukt 2

HCID 807IodineHCID 94750p-tert-Butylanisole

Produkt 1

HCID 14914462HCID 14914462, Verbindung

Reagenzien, Katalysatoren, Lösungsmittel 2

HCID 178418844HCID 178418844, VerbindungKatalysatorHCID 887MethanolLösungsmittel2×

Versuchsvorschrift

A solution of 1-tert-butyl-4-methoxybenzene (0.10 g, 0.61 mmol) in MeOH (2 mL) was added to a mixture of silver sulfate (0.19 g, 0.61 mmol) and iodine (0.154 g, 0.61 mmol) in MeOH (1 mL). The mixture was stirred at room temperature for 1 h. The mixture was filtered. The filtrate was concentrated. The title compound was obtained. 1H NMR (CDCl3, 500 MHz): δ 7.82 (d, J=2.5 Hz, 1H), 7.36 (dd, J=8.5, 2.5 Hz, 1H), 6.80 (d, J=8.5 Hz, 1H), 1.35 (s, 9H).

Aufarbeitung

  1. filtrationThe mixture was filtered
  2. concentrationThe filtrate was concentrated

Quellen und Nachweise

ORD-Eintrag
ord-820399b07cbd40e9afa496966b93236e
Quelldatensatz
uspto-grants-2011_03
Patentnummer
US07910592B2

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