Dibutylamine → 3-(Dibutylamino)-7-(dipropylamino)phenothiazin-5-ium iodide

HRID 605505

Reaktionsgleichung

Reaktionsgleichung von HRID 605505
[I-:1].[I-].[I-].[CH2:4]([N:7]([C:11]1[CH:12]=[CH:13][C:14]2[C:23]([CH:24]=1)=[S+:22][C:21]1[C:16](=[CH:17][CH:18]=[CH:19][CH:20]=1)[N:15]=2)[CH2:8][CH2:9][CH3:10])[CH2:5][CH3:6].C(N([C:32]1[CH:33]=[CH:34][C:35]2C(C=1)=[S+]C1[C:37](=[CH:38][CH:39]=[CH:40]C=1)[N:36]=2)CCC)CC.C(N(C1C=CC2C(C=1)=[S+]C1C(=CC=CC=1)N=2)CCC)CC.C(NCCCC)CCC>>[I-:1].[CH2:35]([N:36]([C:19]1[CH:18]=[CH:17][C:16]2[C:21]([CH:20]=1)=[S+:22][C:23]1[C:14](=[CH:13][CH:12]=[C:11]([N:7]([CH2:8][CH2:9][CH3:10])[CH2:4][CH2:5][CH3:6])[CH:24]=1)[N:15]=2)[CH2:37][CH2:38][CH2:39][CH3:40])[CH2:34][CH2:33][CH3:32]

Komponenten

3

Edukt 2

HCID 8148DibutylamineHCID 178457153HCID 178457153, Verbindung

Produkt 1

HCID 1784490283-(Dibutylamino)-7-(dipropylamino)phenothiazin-5-ium iodide

Versuchsvorschrift

This compound was obtained following isolation of 3-(N,N-dipropylamino)-phenothiazin-5-ium triiodide and subsequent treatment with dibutylamine. Precipitation from dichloromethane by addition of diethyl ether yielded purple lustrous crystals. Mass spectrometry: C26H38N3OS requires m/z=424; found m/z=424 (I− not detected by mass spectrometry).

Aufarbeitung

  1. customThis compound was obtained
  2. customPrecipitation from dichloromethane
  3. additionby addition of diethyl ether yielded purple lustrous crystals

Quellen und Nachweise

ORD-Eintrag
ord-054a48a72c13406192f3d395c4d281a1
Quelldatensatz
uspto-grants-2011_03
Patentnummer
US07915254B2

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