4'-Mercaptoacetanilide → N-[4-(4-Methyl-2-nitro-phenylsulfanyl)-phenyl]-acetamide
Reaktionsgleichung
[CH3:1][C:2]1[CH:7]=[CH:6][C:5](OS(C(F)(F)F)(=O)=O)=[C:4]([N+:16]([O-:18])=[O:17])[CH:3]=1.[SH:19][C:20]1[CH:25]=[CH:24][C:23]([NH:26][C:27](=[O:29])[CH3:28])=[CH:22][CH:21]=1>>[CH3:1][C:2]1[CH:7]=[CH:6][C:5]([S:19][C:20]2[CH:21]=[CH:22][C:23]([NH:26][C:27](=[O:29])[CH3:28])=[CH:24][CH:25]=2)=[C:4]([N+:16]([O-:18])=[O:17])[CH:3]=1Komponenten
3
Versuchsvorschrift
The product from Example 6a (1 g, 3.51 mmol) was reacted with N-(4-mercapto-phenyl)-acetamide (0.65 g, 351 mmol) for 18 h following the procedure from Example 6b giving the title compound (1.04 g, 98%).
Quellen und Nachweise
- ORD-Eintrag
- ord-39e32e6d448745d7a8e72c2e6f042e01
- Quelldatensatz
- uspto-grants-2011_03