HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
Benzene, [1-[(trimethylsilyl)oxy]ethenyl]- → 4-Hydroxy-3-[(2-naphthalenylmethyl)thio]-6-phenyl-2H-pyran-2-one
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | Benzene, [1-[(trimethylsilyl)oxy]ethenyl]- | HCID 117406 | — |
| Edukt | [(2-Naphthalenylmethyl)thio]propanedioic acid | HCID 19596193 | — |
| Produkt | 4-Hydroxy-3-[(2-naphthalenylmethyl)thio]-6-phenyl-2H-pyran-2-one | HCID 54681494 | — |
Reaktionsschritte
The title compound was prepared by Method A using 1-phenyl-1-(trimethylsilyloxy)ethylene (0.475 g, 2.46 mmol) and dimethyl ester of [(2-naphthalenylmethyl)thio]propanedioic acid (0.500 g, 1.64 mmol). m.p. dec>250° C.; 1H NMR (250 MHz, DMSO-d6) δ4.06 (s, 2 H), 6.47 (s, 1 H), 7.46 (m, 6 H), 7.78 (m, 6 H).
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US06005103 |
| Quelldatensatz | uspto-grants-1999_12 |
| ORD ID | ord-cd11143dd647424f8647ff596af96881 |
| Quellennotiz | uspto-grants-1999_12 |