Trimethylolpropane → 2-Hexyl-1-decanol

Reaktionsgleichung

[CH2:1](C(CO)(CO)CC)[OH:2].C[CH:11]([CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][C:25](O)=O)[CH3:12]>>[CH2:20]([CH:19]([CH2:18][CH2:17][CH2:16][CH2:15][CH2:14][CH2:13][CH2:11][CH3:12])[CH2:1][OH:2])[CH2:21][CH2:22][CH2:23][CH2:24][CH3:25]

Komponenten

Edukt 2

HCID 6510Trimethylolpropane

HCID 3624714-Methylpentadecanoic acid

Produkt 1

HCID 953372-Hexyl-1-decanol

Versuchsvorschrift

The ester oil of claim 1 being the monoisopalmitic acid-di-n-C8-10 alkanoic acid ester of trimethylolpropane, said isopalmitic acid being obtained by the oxidation of 2-hexyldecanol formed from n-octanol by the Guerbet synthesis.

Quellen und Nachweise

ORD-Eintrag: ord-ddcf8f49087c447d9b4678c6819ec5bc
Quelldatensatz: uspto-grants-1979_03
DOI: 10.6084/m9.figshare.5104873.v1
Patentnummer: US04144183

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