Thionyl Chloride → 4-Hexadecylaminobenzoyl chloride hydrochloride
Reaktionsgleichung
[ClH:1].[CH2:2]([NH:18][C:19]1[CH:27]=[CH:26][C:22]([C:23](O)=[O:24])=[CH:21][CH:20]=1)[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH3:17].S(Cl)([Cl:30])=O>>[ClH:30].[CH2:2]([NH:18][C:19]1[CH:27]=[CH:26][C:22]([C:23]([Cl:1])=[O:24])=[CH:21][CH:20]=1)[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH3:17]Komponenten
3
Versuchsvorschrift
A mixture of 1.00 g of 4-(n-hexadecylamino)benzoic acid hydrochloride and 5.00 ml of thionyl chloride is allowed to stand at ambient temperature for 20 hours and then is concentrated in vacuo to yield 4-(n-hexadecylamino)benzoyl chloride hydrochloride as an orange solid.
Aufarbeitung
- concentrationis concentrated in vacuo
Quellen und Nachweise
- ORD-Eintrag
- ord-14331f94204e4190a4b3c5f5f11a0a63
- Quelldatensatz
- uspto-grants-1979_03