Benzoyl chloride → HCID 70477659, Verbindung

HRID 615309

Reaktionsgleichung

Reaktionsgleichung von HRID 615309
[Al+3].[Cl-].[Cl-].[Cl-].[C:5](Cl)(=[O:12])[C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1.[C:14]1([CH:20]([CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH3:39])[C:21]([OH:23])=[O:22])[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1>C(Cl)(Cl)(Cl)Cl>[C:5]([C:20]([C:14]1[CH:15]=[CH:16][CH:17]=[CH:18][CH:19]=1)([CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH3:39])[C:21]([OH:23])=[O:22])(=[O:12])[C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1

Komponenten

5

Edukt 3

HCID 7412Benzoyl chlorideHCID 6451240Aluminum(III) ChlorideHCID 220152372-Phenyloctadecanoic acid

Produkt 1

HCID 70477659HCID 70477659, VerbindungAusbeute 40,4 %

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 5943Carbon TetrachlorideLösungsmittel

Versuchsvorschrift

To a one-liter glass reactor equipped with a mechanical stirrer, condenser, thermometer and addition funnel was charged 300 mls freshly distilled carbon tetrachloride. The flask and its contents were cooled to 0°-5° C. and 40 grams (0.30 mole) AlCl3 added slowly. This was followed by the dropwise addition of 42 grams (0.30 mole) benzoyl chloride and then 26.9 grams (0.075 mole) phenylstearic acid. The mixture was maintained at 0°-5° C. for one hour with agitation and then allowed to warm to room temperature and stirred overnight. A yield of 40.4 percent crude benzoylphenylstearic acid was obtained upon work up of the reaction mixture.

Aufarbeitung

  1. customTo a one-liter glass reactor equipped with a mechanical stirrer, condenser
  2. additionthermometer and addition funnel
  3. temperatureThe flask and its contents were cooled to 0°-5° C.
  4. temperatureThe mixture was maintained at 0°-5° C. for one hour with agitation

Quellen und Nachweise

ORD-Eintrag
ord-a7c93e238e834ea980ec7e1b5bd81082
Quelldatensatz
uspto-grants-1985_02
Patentnummer
US04499013

Verknüpfte Notizen

Wird geladen…