2-Tetralone → 3-Bromo-6,6-dimethyl-5,6-dihydro-benzo[b]carbazol-11-one

Reaktionsgleichung

[Br:1][C:2]1[CH:14]=[C:13]2[C:5]([C:6]3[C:7](=[O:23])[C:8]4[CH:20]=[CH:19][C:18](OC)=[CH:17][C:9]=4[C:10]([CH3:16])([CH3:15])[C:11]=3[NH:12]2)=[CH:4][CH:3]=1.C1C2C(=CC=CC=2)CCC1=O>>[Br:1][C:2]1[CH:14]=[C:13]2[C:5]([C:6]3[C:7](=[O:23])[C:8]4[CH:20]=[CH:19][CH:18]=[CH:17][C:9]=4[C:10]([CH3:15])([CH3:16])[C:11]=3[NH:12]2)=[CH:4][CH:3]=1

Komponenten

Edukt 2

HCID 682662-Tetralone

HCID 668342923-Bromo-8-methoxy-6,6-dimethyl-5,6-dihydrobenzo[b]carbazol-11-one

Produkt 1

HCID 668345403-Bromo-6,6-dimethyl-5,6-dihydro-benzo[b]carbazol-11-one

Versuchsvorschrift

Under the same conditions as the method for synthesizing Compound A3-1 and Compound A4, the title compound was prepared from 3,4-dihydro-1H-naphthalen-2-one (560 mg).

Quellen und Nachweise

ORD-Eintrag: ord-0dea57aa58554d7cb5461ac5dfceedfb
Quelldatensatz: uspto-grants-2016_09
DOI: 10.6084/m9.figshare.5104873.v1
Patentnummer: US09440922B2

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