Diphenyl Ether → HCID 178439550, Verbindung
Reaktionsgleichung
C([O:4][C:5]1[C:14]2[C:9](=[CH:10][CH:11]=[C:12]([O:15][CH3:16])[CH:13]=2)[N:8]=[CH:7][CH:6]=1)C=C.[C:17]1(OC2C=CC=CC=2)[CH:22]=CC=C[CH:18]=1>>[CH2:22]([C:6]1[CH:7]=[N:8][C:9]2[C:14]([C:5]=1[OH:4])=[CH:13][C:12]([O:15][CH3:16])=[CH:11][CH:10]=2)[CH:17]=[CH2:18]Komponenten
3
Versuchsvorschrift
A solution of 4-allyloxy-6-methoxy-quinoline (4.0 g, 18.6 mmol, 1.0 eq) in diphenyl oxide (80 mL) is heated at 180° C. for 1 hour. The reaction mixture is then cooled down to room temperature before the addition of petroleum ether (100 mL). The resulting suspension is filtered to afford 3-allyl-6-methoxy-quinolin-4-ol as a light grey solid (1.3 g, 32% yield).
Aufarbeitung
- filtrationThe resulting suspension is filtered
Quellen und Nachweise
- ORD-Eintrag
- ord-9a14b67aa14040768ccd5412775e2a2f