Reaktionsgleichung
C#C.[CH:3]([Si:5]([N:12]([CH3:14])[CH3:13])([N:9]([CH3:11])[CH3:10])[N:6]([CH3:8])[CH3:7])=[CH2:4]>>[CH2:3]([Si:5]([N:9]([CH3:10])[CH3:11])([N:6]([CH3:8])[CH3:7])[N:12]([CH3:13])[CH3:14])[CH3:4]Komponenten
3
Reaktionsbedingungen
- Temperatur
- 240 °C
Versuchsvorschrift
The reaction was carried out as in Example 3; however, the acetylene pressure was increased to 150 psig and the reaction temperature was maintained at 240° C. Vinyltris(dimethylamino)silane was the single major product at a yield of 85% theoretical. Ethyltris(dimethylamino)silane and 1,2-bis(trisdimethylamino)silylethane were also formed, each in approximately a 2 to 3% yield. Vinyltris(dimethylamino)silane was also formed in approximately 10% yield.
Quellen und Nachweise
- ORD-Eintrag
- ord-51e82ae9882b46439ba9ab11a5f08b0c
- Quelldatensatz
- uspto-grants-1985_12
- Patentnummer
- US04558146
Verknüpfte Notizen
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