tert-Butyl methylcarbamate → 1,1-Dimethylethyl (4-formyl-3-methylphenyl)methylcarbamate

HRID 644743Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 644743
Br[C:2]1[CH:9]=[CH:8][C:5]([CH:6]=[O:7])=[C:4]([CH3:10])[CH:3]=1.[CH3:11][NH:12][C:13](=[O:19])[O:14][C:15]([CH3:18])([CH3:17])[CH3:16]>>[CH:6]([C:5]1[CH:8]=[CH:9][C:2]([CH2:11][NH:12][C:13](=[O:19])[O:14][C:15]([CH3:18])([CH3:17])[CH3:16])=[CH:3][C:4]=1[CH3:10])=[O:7]

Komponenten

3

Edukt 2

HCID 527635tert-Butyl methylcarbamateHCID 135551504-Bromo-2-methylbenzaldehyde

Produkt 1

HCID 866181121,1-Dimethylethyl (4-formyl-3-methylphenyl)methylcarbamate

Versuchsvorschrift

The title compound was prepared from crude 4-bromo-2-methylbenzaldehyde (D91) and 1,1-dimethylethyl methylcarbamate (D83) using a method similar to that described for D84 in Description 84. δH (CDCl3, 400 MHz) 10.20 (1H, s), 7.76 (1H, d), 7.28 (1H, dd), 7.19 (1H, d), 3.31 (3H, s), 2.66 (3H, s), 1.49 (9H, s).

Quellen und Nachweise

ORD-Eintrag
ord-a40fb7f683f64bb291d5ebb794f090bb
Quelldatensatz
uspto-grants-2010_04
Patentnummer
US07700599B2

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