Triethanolamine → Ethyl (2-cyanoaziridin-1-yl)acetate
Reaktionsgleichung
Cl.Br[CH:3]([CH2:6][NH:7][CH2:8][C:9]([O:11][CH2:12][CH3:13])=[O:10])[C:4]#[N:5].N(CCO)(CCO)CCO>>[C:4]([CH:3]1[CH2:6][N:7]1[CH2:8][C:9]([O:11][CH2:12][CH3:13])=[O:10])#[N:5]Komponenten
3
Versuchsvorschrift
reaction of 2-bromo-3-(carbethoxymethylamino)-propionitrile hydrochloride (prepared by reacting 2,3-dibromopropionitrile with glycine ethyl ester; m.p. 70°-75° C.) with triethanolamine gives ethyl 2-cyano-1-aziridine-acetate; b.p.0.1 : 88°-90° C.; yield 34% of theory;
Quellen und Nachweise
- ORD-Eintrag
- ord-3f569ecccba04aaa8b6ff5fd29542b9e
- Quelldatensatz
- uspto-grants-1983_10
- Patentnummer
- US04410532
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