Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|
| Edukt | Benzoyl chloride | HCID 7412 | — |
| Edukt | Dimethyl Carbonate | HCID 12021 | — |
| Katalysator | Lithium Chloride | HCID 433294 | — |
| Lösungsmittel | Sulfolane | HCID 31347 | — |
| Produkt | Methyl Benzoate | HCID 7150 | 70,1% |
Reaktionsschritte
The following example illustrates the use of alkali halide catalysts. A mixture of benzoyl chloride (7.03 g, 0.05 mole), dimethyl carbonate (4.5 g, 0.05 mole) and lithium chloride (0.106 g, 0.0025 mole) in 25 ml of sulfolane was heated to 150° C. for 22 hours. Distillation of the reaction mixture gave 4.77 g (70 percent yield) methyl benzoate.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patentnummer | US04612386 |
|---|
| Quelldatensatz | uspto-grants-1986_09 |
|---|
| ORD ID | ord-ee2e26d06a894ead8746b98001a992e8 |
|---|
| Quellennotiz | uspto-grants-1986_09 |
|---|
