Ammonia → 1-Amino-1-[4-methylpiperazino]-2-nitroethene
Reaktionsgleichung
CS[C:3](SC)=[CH:4][N+:5]([O-:7])=[O:6].[CH3:10][N:11]1[CH2:16][CH2:15][NH:14][CH2:13][CH2:12]1.[NH3:17]>ClCC(Cl)(Cl)Cl>[NH2:17][C:3]([N:14]1[CH2:15][CH2:16][N:11]([CH3:10])[CH2:12][CH2:13]1)=[CH:4][N+:5]([O-:7])=[O:6]Komponenten
5
Edukt 3
Produkt 1
Reagenzien, Katalysatoren, Lösungsmittel 1
Versuchsvorschrift
An amount of 16.5 g of 1,1-bis-(methylthio)-2-nitroethene is dissolved at high temperature in 100 ml of tetrachloroethane, equimolar amounts of methyl-piperazine are added, the mixture is refluxed over 2 hours; the mass is cooled and anhydrous gaseous ammonia is added to it up to saturation.
Aufarbeitung
- temperaturethe mixture is refluxed over 2 hours
- temperaturethe mass is cooled
Quellen und Nachweise
- ORD-Eintrag
- ord-67ce7d1c8b6e4df0965b3debb666c260
- Quelldatensatz
- uspto-grants-1986_09
- Patentnummer
- US04613602
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