4-Dodecylaniline → N-(p-dodecylphenyl)-2,4,6-triphenylpyridinium triflate

HRID 652692Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 652692
[O-:1][S:2]([C:5]([F:8])([F:7])[F:6])(=[O:4])=[O:3].[C:9]1([C:15]2[CH:20]=[C:19]([C:21]3[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=3)[CH:18]=[C:17]([C:27]3[CH:32]=[CH:31][CH:30]=[CH:29][CH:28]=3)[O+]=2)[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1.[CH2:33]([C:45]1[CH:51]=[CH:50][C:48]([NH2:49])=[CH:47][CH:46]=1)[CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH2:43][CH3:44]>C(O)C>[O-:4][S:2]([C:5]([F:8])([F:7])[F:6])(=[O:3])=[O:1].[CH2:33]([C:45]1[CH:46]=[CH:47][C:48]([N+:49]2[C:15]([C:9]3[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=3)=[CH:20][C:19]([C:21]3[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=3)=[CH:18][C:17]=2[C:27]2[CH:32]=[CH:31][CH:30]=[CH:29][CH:28]=2)=[CH:50][CH:51]=1)[CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH2:43][CH3:44]

Komponenten

4

Edukt 2

HCID 77014-DodecylanilineHCID 2778031AG-G-77560

Produkt 1

HCID 20064835N-(p-dodecylphenyl)-2,4,6-triphenylpyridinium triflate

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 702EthanolLösungsmittel

Versuchsvorschrift

A 2.3-g portion (0.005 mole) of 2,4,6-triphenylpyrylium triflate is placed in a 500-ml round-bottom flask. To this, 200 ml of ethanol is added and then 1.3 g (0.005 mole) of p-dodecylaniline is added. The mixture is refluxed for about 20 hours. The ethanol is removed by evaporation to give a yellow waxy substance. This material is washed with ether which causes some yellow crystals to precipitate.

Aufarbeitung

  1. temperatureThe mixture is refluxed for about 20 hours
  2. customThe ethanol is removed by evaporation
  3. customto give a yellow waxy substance
  4. washThis material is washed with ether which
  5. customto precipitate

Quellen und Nachweise

ORD-Eintrag
ord-6083bbd623384562972508b13ce9f068
Quelldatensatz
uspto-grants-1987_06
Patentnummer
US04672118

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