Phenylisohexanol → (E)-3-(4-Diethylamino-2-hydroxy-phenyl)-but-2-enoic acid 3-methyl-5-phenyl-pentyl ester
Reaktionsgleichung
[CH3:1][CH:2]([CH2:23][CH2:24][C:25]1[CH:30]=[CH:29][CH:28]=[CH:27][CH:26]=1)[CH2:3][CH2:4][O:5][C:6](=[O:22])[CH:7]=[C:8]([C:10]1[CH:15]=[CH:14][C:13]([N:16]([CH2:19][CH3:20])[CH2:17][CH3:18])=[CH:12][C:11]=1[OH:21])[CH3:9].C(OC(=O)C=C(C1C=CC(N(CC)CC)=CC=1O)C)C.CC(CCC1C=CC=CC=1)CCO>>[CH3:1][CH:2]([CH2:23][CH2:24][C:25]1[CH:30]=[CH:29][CH:28]=[CH:27][CH:26]=1)[CH2:3][CH2:4][O:5][C:6](=[O:22])/[CH:7]=[C:8](/[C:10]1[CH:15]=[CH:14][C:13]([N:16]([CH2:17][CH3:18])[CH2:19][CH3:20])=[CH:12][C:11]=1[OH:21])\[CH3:9]Komponenten
4
Edukt 3
Produkt 1
Versuchsvorschrift
According to the same procedure, 3-(4-diethylamino-2-hydroxy-phenyl)-but-2-enoic acid 3-methyl-5-phenyl-pentyl ester was prepared from 3-(4-diethylamino-2-hydroxy-phenyl)-but-2-enoic acid ethyl ester, 3-methyl-5-phenyl-pentanol and tetraisopropyl-o-titanate.