Oxygen → 1-[3-(3,3-Dimethylbutoxy)-5-ethoxyphenyl]ethanone

HRID 657959Notizen

Reaktionsgleichung

[OH:1][C:2]1[CH:3]=[C:4]([C:9](=[O:11])[CH3:10])[CH:5]=[C:6]([OH:8])[CH:7]=1.O=O.[CH:14]1(Br)CCCC[CH2:15]1.Br[CH2:22][CH2:23][C:24]([CH3:27])([CH3:26])[CH3:25]>>[CH3:25][C:24]([CH3:27])([CH3:26])[CH2:23][CH2:22][O:1][C:2]1[CH:3]=[C:4]([C:9](=[O:11])[CH3:10])[CH:5]=[C:6]([O:8][CH2:14][CH3:15])[CH:7]=1

Komponenten

Edukt 4

HCID 977Oxygen

HCID 7960Cyclohexyl bromide

HCID 1039933',5'-Dihydroxyacetophenone

HCID 1371371-Bromo-3,3-dimethylbutane

Produkt 1

HCID 581368231-[3-(3,3-Dimethylbutoxy)-5-ethoxyphenyl]ethanone

Versuchsvorschrift

1-(3,5-Dihydroxyphenyl)ethanone (3.0 g) was converted analogously to O2.031. Instead of cyclohexylbromide, however, 1-bromo-3,3-dimethylbutane was used. After chromatography, 960 mg of the title compound were obtained.

Quellen und Nachweise

ORD-Eintrag: ord-bba8b21f77754324b9d418114a0d3d1d
Quelldatensatz: uspto-grants-2011_12
DOI: 10.6084/m9.figshare.5104873.v1
Patentnummer: US08076336B2

Notizen zur Reaktion

Wird geladen…