Acetate → Ethyl 3-{[tert-butyl(dimethyl)silyl]oxy}bicyclo[3.1.0]hexane-6-carboxylate

HRID 681456

Reaktionsgleichung

[C:1]([CH3:2])([CH3:3])([CH3:4])[Si:5]([CH3:6])([CH3:7])[O:8][CH:9]1[CH2:10][CH:11]=[CH:12][CH2:13]1.[C:22]([O-:23])(=[O:24])[CH3:25].[C:27]([O-:28])(=[O:29])[CH3:30].[N+:14](=[N-:15])=[CH:16][C:17](=[O:18])[O:19][CH2:20][CH3:21].[Rh+2:26]>>[C:1]([CH3:2])([CH3:3])([CH3:4])[Si:5]([CH3:6])([CH3:7])[O:8][CH:9]1[CH2:10][CH:11]2[CH:12]([CH2:13]1)[CH:16]2[C:17](=[O:18])[O:19][CH2:20][CH3:21]

Komponenten

Edukt 4

HCID 175Acetate2×

HCID 12192Ethyl diazoacetate

HCID 185497Rhodium, ion(Rh2)

HCID 11106335Tert-butyl(cyclopent-3-en-1-yloxy)dimethylsilane

Produkt 1

HCID 67432091Ethyl 3-{[tert-butyl(dimethyl)silyl]oxy}bicyclo[3.1.0]hexane-6-carboxylate

Quellen und Nachweise

ORD-Eintrag: ord-f468c6b114d84982ba6d0c71941c024d
Quelldatensatz: Training data from https://doi.org/10.1039/C8SC04228D (3/10)
DOI: 10.1039/C8SC04228D

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