1,1-Dichlorosilacyclobutane → 1,1-Diacetamidosilacyclobutane

HRID 704072

Reaktionsgleichung

Reaktionsgleichung von HRID 704072
C[Si]([CH2:5][C:6]([NH2:8])=[O:7])(C)C.Cl[Si:10]1(Cl)[CH2:13][CH2:12][CH2:11]1>C(Cl)Cl>[C:6]([NH:8][Si:10]1([NH:8][C:6](=[O:7])[CH3:5])[CH2:13][CH2:12][CH2:11]1)(=[O:7])[CH3:5]

Komponenten

4

Edukt 2

HCID 753731,1-DichlorosilacyclobutaneHCID 357676Acetamide, 2-(trimethylsilyl)-

Produkt 1

HCID 200755231,1-Diacetamidosilacyclobutane

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 6344DichloromethaneLösungsmittel

Versuchsvorschrift

When 1.72 g of trimethylsilylacetamide was mixed with 0.92 g of 1,1-dichlorosilacyclobutane in 5 g of methylene chloride, a white precipitate formed. The precipitate dissoved upon shaking and slowly recrystallized as white needles. There was no trimethylchlorosilane detected in the residual fluid, indicating that the expected reaction to form 1,1-diacetamidosilacyclobutane did not occur.

Aufarbeitung

  1. customa white precipitate formed
  2. customslowly recrystallized as white needles
  3. customreaction

Quellen und Nachweise

ORD-Eintrag
ord-c2cd10faa21e40fbbb19209d3ea4c1b8
Quelldatensatz
uspto-grants-1991_01
Patentnummer
US04985565

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