1-Bromo-4-(trimethoxymethyl)benzene → 1-(4-Bromophenyl)-4-t-butyl-2,6-dioxa-7-thiabicyclo[2,2,2]octane
Reaktionsgleichung
[OH:1][CH2:2][C:3]([CH2:10][OH:11])([C:6]([CH3:9])([CH3:8])[CH3:7])[CH2:4][SH:5].CO[C:14](OC)(OC)[C:15]1[CH:20]=[CH:19][C:18]([Br:21])=[CH:17][CH:16]=1>>[Br:21][C:18]1[CH:19]=[CH:20][C:15]([C:14]23[S:5][CH2:4][C:3]([C:6]([CH3:7])([CH3:8])[CH3:9])([CH2:10][O:11]2)[CH2:2][O:1]3)=[CH:16][CH:17]=1Komponenten
3
Versuchsvorschrift
From 2,2-di-hydroxymethyl-3,3-dimethyl-butan-1-thiol and trimethyl 4-bromo-orthobenzoate, trimethyl 4-chloro-orthobenzoate, trimethyl orthocyclohexylcarboxylate and trimethyl ortho-cycloheptylcarboxylate in the manner described previously, the following compounds were prepared:
Aufarbeitung
- customthe following compounds were prepared
Quellen und Nachweise
- ORD-Eintrag
- ord-02819a222c84480d8746b7e2611a3ae6