HCID 86729487, Verbindung → HCID 68539279, Verbindung

HRID 712443Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 712443
C([N:8]1[CH2:12][CH:11]2[CH2:13][CH2:14][O:15][CH2:16][CH:10]2[CH2:9]1)C1C=CC=CC=1>CCO.[OH-].[OH-].[Pd+2]>[CH2:12]1[NH:8][CH2:9][CH:10]2[CH2:16][O:15][CH2:14][CH2:13][CH:11]12

Komponenten

4

Edukt 1

HCID 86729487HCID 86729487, Verbindung

Produkt 1

HCID 68539279HCID 68539279, VerbindungAusbeute 53,2 %

Reagenzien, Katalysatoren, Lösungsmittel 2

HCID 9942167Palladium hydroxideKatalysatorHCID 702EthanolLösungsmittel

Versuchsvorschrift

To a solution of 2-benzyloctahydropyrano[3,4-c]pyrrole (0.45 g) in EtOH (30 mL) was added 20% Pd(OH)2 (0.30 g). The suspension was stirred under H2 for 12 h and filtered. The filtrate was concentrated in vacuo to give the title compound (0.14 g). The compound was characterized by the following spectroscopic data: MS (ESI, pos. ion) m/z: 128.3 (M+1).

Aufarbeitung

  1. filtrationfiltered
  2. concentrationThe filtrate was concentrated in vacuo

Quellen und Nachweise

ORD-Eintrag
ord-b58a8a70399d4663bf32285064d66fcd
Quelldatensatz
uspto-grants-2015_11
Patentnummer
US09181277B2

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