HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
2-Methylresorcinol → 3-(Cyclohexylmethoxy)-2-methylphenol
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | 2-Methylresorcinol | HCID 11843 | — |
| Edukt | Cyclohexane, (bromomethyl)- | HCID 137636 | — |
| Produkt | 3-(Cyclohexylmethoxy)-2-methylphenol | HCID 43143282 | — |
Reaktionsschritte
Alkylation of 2-methylbenzene-1,3-diol using (bromomethyl)cyclohexane following the method used in Example 154 gave 3-(cyclohexylmethoxy)-2-methylphenol. Yield (0.58 g, 37%): 1H NMR (400 MHz, CDCl3) δ 6.98 (t, J=8.0 Hz, 1H), 6.42 (t, J=7.6 Hz, 2H), 4.60 (bs, 1H), 3.72 (d, J=6.4 Hz, 2H), 2.12 (s, 3H), 1.68-1.89 (m, 6H), 1.16-1.35 (m, 3H), 1.01-1.11 (m, 2H).
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US08829244B2 |
| Quelldatensatz | uspto-grants-2014_09 |
| ORD ID | ord-91ea1935be7d4b88b8f46a9d71815531 |
| Quellennotiz | uspto-grants-2014_09 |