Benzaldehyde → 2,2,2-Trichloro-1-phenylethanol
Reaktionsgleichung
C(=O)C1C=CC=CC=1.[CH:9](=[O:18])[C:10]1[CH:15]=[CH:14][C:13]([O:16][CH3:17])=[CH:12][CH:11]=1.[Cl:19][C:20]([CH:23]([OH:33])[C:24]1[CH:29]=[CH:28][CH:27]=[C:26]([N+]([O-])=O)[CH:25]=1)([Cl:22])[Cl:21]>>[Cl:19][C:20]([CH:23]([OH:33])[C:24]1[CH:25]=[CH:26][CH:27]=[CH:28][CH:29]=1)([Cl:21])[Cl:22].[Cl:19][C:20]([CH:9]([OH:18])[C:10]1[CH:15]=[CH:14][C:13]([O:16][CH3:17])=[CH:12][CH:11]=1)([Cl:22])[Cl:21]Komponenten
5
Versuchsvorschrift
Following the procedure of Example I and substituting benzaldehyde, 4-anisaldehyde and other starting material compounds and substituting the reagents of Example II, there is obtained trichloromethylbenzyl alcohol, trichloromethyl-4-methoxybenzyl alcohol and the benzaldehyde corresponding to said starting material compound, respectively.