1,3,5,7-Tetrahydroxyadamantane → 1,3,5,7-Tetrakisacryloyloxy(fluoroadamantane)

HRID 749652Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 749652
FC1C2(O)CC3CC(O)(CC1(O)C3)C2.OC12CC3(O)CC(O)(CC(O)(C3)C1)C2.[C:29]([O:33][C:34]12[C:54](F)(F)[C:38]3([O:57][C:58](=[O:61])[CH:59]=[CH2:60])[C:39](F)(F)[C:40]([O:47][C:48](=[O:51])[CH:49]=[CH2:50])([C:44](F)(F)[C:36]([O:64][C:65](=[O:68])[CH:66]=[CH2:67])([C:37]3(F)F)[C:35]1(F)F)[C:41]2(F)[F:42])(=[O:32])[CH:30]=[CH2:31]>>[C:48]([O:47][C:40]12[CH2:44][C:36]3([O:64][C:65](=[O:68])[CH:66]=[CH2:67])[CH2:37][C:38]([O:57][C:58](=[O:61])[CH:59]=[CH2:60])([CH2:54][C:34]([O:33][C:29](=[O:32])[CH:30]=[CH2:31])([CH2:35]3)[CH:41]1[F:42])[CH2:39]2)(=[O:51])[CH:49]=[CH2:50]

Komponenten

4

Edukt 3

HCID 8200931,3,5,7-TetrahydroxyadamantaneHCID 69001959Fluoro(1,3,5-trihydroxyadamantane)HCID 866128691,3,5,7-Tetrakisacryloyloxy(perfluoroadamantane)

Produkt 1

HCID 690018651,3,5,7-Tetrakisacryloyloxy(fluoroadamantane)

Versuchsvorschrift

The same reactions as in Examples 1-1 to 1-4 are carried out except that 1,3,5-trihydroxyadamantane used in Example 1-1 is changed to 1,3,5,7-tetrahydroxyadamantane, whereupon formation of 1,3,5,7-tetrakisacryloyloxy(perfluoroadamantane) is confirmed. Further, formation of 2-hydro-1,3,5,7-tetrakisacryloyloxy(perfluoroadamantane) is confirmed.

Quellen und Nachweise

ORD-Eintrag
ord-f0fd735eb68443f789e45d2782890cc0
Quelldatensatz
uspto-grants-2008_07
Patentnummer
US07402714B2

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