Santene → (Methylcyclopentylmethyl)dimethyl-bicyclo[2.2.1]heptane

HRID 749655Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 749655
C=[C:2]1[CH:7]([CH3:8])[CH:6]2[CH2:9][CH:3]1[CH2:4][CH2:5]2.C[C:11]1[CH:12]2[CH2:18][CH:15]([C:16]=1C)[CH2:14][CH2:13]2.[CH3:19]C(C1C=C(NC(NC2C=CC(OCC(O)CNC(C)(C)C)=C(C(C)=O)C=2)=O)C=CC=1OCC(O)CNC(C)(C)C)=O.[H][H]>[Ni]>[CH3:14][CH:13]([C:7]1([CH3:8])[CH2:2][CH:3]2[CH2:9][C:6]1([CH3:19])[CH2:5][CH2:4]2)[CH:12]1[CH2:18][CH2:15][CH2:16][CH2:11]1

Komponenten

6

Edukt 4

HCID 10720SanteneHCID 147890Urea, N,N'-bis(3-acetyl-4-(3-((1,1-dimethylethyl)amino)-2-hydroxypropoxy)phenyl)-HCID 123044203-Methyl-2-methylenenorbornaneHCID 178418361HCID 178418361, Verbindung

Produkt 1

HCID 91602681(Methylcyclopentylmethyl)dimethyl-bicyclo[2.2.1]heptane

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 935NickelKatalysator

Versuchsvorschrift

Into a 2 liter autoclave, 1,500 g of the dimer of olefins containing 2-methylene-3-methylbicyclo[2.2.1]heptane and 2,3-dimethylbicyclo[2.2.1]-hept-2-ene as the major components which was obtained in Comparative Example 1 was placed and the resultant mixture was heated at 300° C. for 7 hours under stirring. After the reaction mixture was cooled, 30 g of a nickel/diatomaceous earth catalyst for hydrogenation (manufactured by NIKKI CHEMICAL Co., Ltd.; “N-113”) was added, and the hydrogenation was conducted (the hydrogen pressure: 3 MPa; the reaction temperature: 250° C.; the reaction time: 5 hours). After the reaction was completed, the catalyst was removed by filtration. The filtrate was rectified under a reduced pressure, and 155 g of (methylcyclopentylmethyl)dimethyl-bicyclo[2.2.1]heptane (Fluid 24) was obtained as a fraction having a boiling point in the range of 127 to 130° C./9,060 Pa. Fluid 24 was mixed with Fluid A obtained in Comparative Example 1 in an amount such that the content of Fluid 24 in the entire fluid was 10% by weight. The results of the measurements of the properties and the traction coefficient of the fluid are shown in Table 7.

Aufarbeitung

  1. customwas obtained in Comparative Example 1
  2. temperatureAfter the reaction mixture was cooled
  3. custom250° C.
  4. custom5 hours
  5. customthe catalyst was removed by filtration

Quellen und Nachweise

ORD-Eintrag
ord-693312d1298044d7bf2eee5ebb74370d
Quelldatensatz
uspto-grants-2008_07
Patentnummer
US07402715B2

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