Benzene, 1-iodo-4-(trifluoromethyl)- → HCID 68453189, Verbindung

HRID 751185Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 751185
I[C:2]1[CH:7]=[CH:6][C:5]([C:8]([F:11])([F:10])[F:9])=[CH:4][CH:3]=1.[CH2:12]([OH:17])[CH2:13][CH2:14][C:15]#[CH:16]>C1C=CC([P]([Pd]([P](C2C=CC=CC=2)(C2C=CC=CC=2)C2C=CC=CC=2)([P](C2C=CC=CC=2)(C2C=CC=CC=2)C2C=CC=CC=2)[P](C2C=CC=CC=2)(C2C=CC=CC=2)C2C=CC=CC=2)(C2C=CC=CC=2)C2C=CC=CC=2)=CC=1>[F:9][C:8]([F:11])([F:10])[C:5]1[CH:6]=[CH:7][C:2]([C:16]#[C:15][CH2:14][CH2:13][CH2:12][OH:17])=[CH:3][CH:4]=1

Komponenten

4

Edukt 2

HCID 67993Benzene, 1-iodo-4-(trifluoromethyl)-HCID 793464-Pentyn-1-ol

Produkt 1

HCID 68453189HCID 68453189, Verbindung

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 178418397HCID 178418397, VerbindungKatalysator

Versuchsvorschrift

In analogy to the procedure described in example 1 a], 1-iodo-4-trifluoromethyl-benzene was reacted with 4-pentyn-1-ol in the presence of Pd(PPh3)4 and cuprous iodide to give the title compound as yellow oil.

Quellen und Nachweise

ORD-Eintrag
ord-5e69e8394a974cf4b77aea7e69d8ad7f
Quelldatensatz
uspto-grants-2008_07
Patentnummer
US07405236B2

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