2-Aminobiphenyl → N2,N4-bis(2-phenylphenyl)-5-methyl-2,4-pyrimidinediamine
Reaktionsgleichung
[NH2:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][C:3]=1[C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1.Cl[C:15]1[N:20]=[C:19](Cl)[C:18]([CH3:22])=[CH:17][N:16]=1>>[C:8]1([C:3]2[CH:4]=[CH:5][CH:6]=[CH:7][C:2]=2[NH:1][C:15]2[N:20]=[C:19]([NH:1][C:2]3[CH:7]=[CH:6][CH:5]=[CH:4][C:3]=3[C:8]3[CH:9]=[CH:10][CH:11]=[CH:12][CH:13]=3)[C:18]([CH3:22])=[CH:17][N:16]=2)[CH:9]=[CH:10][CH:11]=[CH:12][CH:13]=1Komponenten
3
Versuchsvorschrift
In like manner to the preparation of 5-fluoro-N2,N4-bis(3-hydroxyphenyl)-2,4-pyrimidinediamine, 2-aminobiphenyl and 2,4-dichloro-5-methylpyrimidine were reacted to provide N2,N4-bis(2-phenylphenyl)-5-methyl-2,4-pyrimidinediamine. LCMS: ret. time: 30.47 min.; purity: 91%; MS (m/e): 429 (MH|).
Aufarbeitung
- customwere reacted
Quellen und Nachweise
- ORD-Eintrag
- ord-8335221da65e47e0b28496bd5c47c355
- Quelldatensatz