HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
(4-Phenylsulfanylmethyl-phenyl)-methanol → 4-[(Phenylsulfanyl)methyl]benzaldehyde
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | (4-Phenylsulfanylmethyl-phenyl)-methanol | HCID 59255239 | — |
| Katalysator | HCID 178418406 | HCID 178418406 | — |
| Lösungsmittel | Chloroform | HCID 6212 | — |
| Produkt | 4-[(Phenylsulfanyl)methyl]benzaldehyde | HCID 820241 | 99,9% |
Reaktionsschritte
To a chloroform (10 mL) solution of (4-phenylsulfanylmethyl-phenyl)-methanol (1 g, 4.34 mmol) described in Manufacturing Example 206-1-2 was added manganese dioxide (3.77 g, 43.4 mmol), which was stirred for 15 hours at room temperature. The manganese dioxide was removed with a Celite bed, and the filtrate was concentrated under a reduced pressure to obtain the title compound (990 mg). The title compound was used in the following reaction without any further purification.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US08841327B2 |
| Quelldatensatz | uspto-grants-2014_09 |
| ORD ID | ord-d2e1aca90f0b464ba40b7ec81c7bcbb3 |
| Quellennotiz | uspto-grants-2014_09 |