Sulfuric Acid → HCID 58581836, Verbindung

Reaktionsgleichung

S([O-])([O:4][CH2:5][C:6]([N+:14]([O-:16])=[O:15])([N+:11]([O-:13])=[O:12])[CH2:7][N:8]=[N+:9]=[N-:10])(=O)=O.[Na+].S(=O)(=O)(O)O>>[N:8]([CH2:7][C:6]([N+:11]([O-:13])=[O:12])([N+:14]([O-:16])=[O:15])[CH2:5][OH:4])=[N+:9]=[N-:10]

Komponenten

Edukt 2

HCID 1118Sulfuric Acid

HCID 86660708Sodium 3-azido-2,2-dinitropropyl sulfate

Produkt 1

HCID 58581836HCID 58581836, Verbindung

Versuchsvorschrift

Scheme 3 illustrates the conversion of 2,2-dinitro 1,3-propanediol cyclic sulfate into 3-azido 2,2-dinitropropanol. First, 2,2-dinitro 1,3-propanediol cyclic sulfate is reacted with sodium azide and dimethylformamide (“DMF”) to open the cyclic sulfate and form sodium 3-azido-2,2-dinitropropyl sulfate. After the cyclic sulfate is opened, the sodium 3-azido-2,2-dinitropropyl sulfate is reacted with 20% sulfuric acid to form 3-azido-2,2-dinitropropanol.

Quellen und Nachweise

ORD-Eintrag: ord-ceab3169e0434567a1d9d218c6b97114
Quelldatensatz: uspto-grants-2014_09
DOI: 10.6084/m9.figshare.5104873.v1
Patentnummer: US08841468B2

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