Benzene → HCID 86664985, Verbindung

HRID 83957

Reaktionsgleichung

Reaktionsgleichung von HRID 83957
[CH2:1]=[C:2]1[CH2:7][CH:6]([CH3:8])[O:5][C:3]1=[O:4].C1C=CC=CC=1.[CH:15]([C:17]1[CH:22]=[CH:21][CH:20]=[CH:19][C:18]=1[CH:23]=[CH2:24])=[CH2:16]>>[CH2:1]=[C:2]1[CH2:7][CH:6]([CH3:8])[O:5][C:3]1=[O:4].[CH:15]([C:17]1[CH:22]=[CH:21][CH:20]=[CH:19][C:18]=1[CH:23]=[CH2:24])=[CH2:16]

Komponenten

4

Edukt 3

HCID 241BenzeneHCID 666661,2-DiethenylbenzeneHCID 99939gamma-Methyl-alpha-methylene-gamma-butyrolactone

Produkt 1

HCID 86664985HCID 86664985, Verbindung

Reaktionsbedingungen

Temperatur
65 °C

Versuchsvorschrift

To a dry 100 mL round bottom flask equipped with a magnetic stir bar was charged 1.0153 g (8.98×10−3 mol) α-methylene-γ-valerolactone, 16.78 g (0.215 mol) benzene, 0.0561 g (4.31×10−4 mol) divinyl benzene, and 0.0067 g (4.08×10−5 mol) azobisisobutylnitrile. The reactor was purged with nitrogen for 30 minutes before heating to 65° C. The reactor was held at 65° C. for 5 hours before letting cooling the reaction mixture to room temperature and drying under vacuum.

Aufarbeitung

  1. customTo a dry 100 mL round bottom flask equipped with a magnetic stir bar
  2. customThe reactor was purged with nitrogen for 30 minutes
  3. temperaturebefore letting cooling the reaction mixture to room temperature
  4. customdrying under vacuum

Quellen und Nachweise

ORD-Eintrag
ord-cc45147e8cd34e0daca082f656717305
Quelldatensatz
uspto-grants-2014_09
Patentnummer
US08846817B2

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