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HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
HRID 841152Erstellt: 25. Oktober 2026

Chlorotrimethylsilane → 1-Chloro-3,7-dimethyl-octa-2,6-diene

https://huagongshe.com/reaction/841152

Reaktionsgleichung

Beteiligte Stoffe

RolleNameHCIDEinwaage
EduktChlorotrimethylsilaneHCID 6397—
EduktLinaloolHCID 6549—
KatalysatorBismuthyl (ion)HCID 5237718—
Produkt1-Chloro-3,7-dimethyl-octa-2,6-dieneHCID 9910683,2%

Reaktionsbedingungen

Temperatur60 °C

Reaktionsschritte

To a mixture of 170 g linalool and 20 mg bismuth(III)-oxide heated to 60° C., 130.5 g trimethylchlorosilane were dropped in. Then the mixture was cooled to room temperature and the organic layer was separated. The resulting oil was purified by distillation to yield 158.35 g of a colorless oil.

Herkunft & Nachweise

DOI10.6084/m9.figshare.5104873.v1
PatentnummerUS06369248B1
Quelldatensatzuspto-grants-2002_04
ORD IDord-93b7fdeaec43433281661a380319a923
Quellennotizuspto-grants-2002_04