5-Methylfuran-3-carboxylic acid → 6-(5-methylfur-3-oyl)amino-3-(dimethyl)amino-1,2,3,4-tetrahydro-9H-carbazole
Reaktionsgleichung
[NH2:1][C:2]1[CH:3]=[C:4]2[C:12](=[CH:13][CH:14]=1)[NH:11][C:10]1[CH2:9][CH2:8][CH:7]([N:15]([CH3:17])[CH3:16])[CH2:6][C:5]2=1.[CH3:18][C:19]1[O:23][CH:22]=[C:21]([C:24](O)=[O:25])[CH:20]=1>>[CH3:18][C:19]1[O:23][CH:22]=[C:21]([C:24]([NH:1][C:2]2[CH:3]=[C:4]3[C:12](=[CH:13][CH:14]=2)[NH:11][C:10]2[CH2:9][CH2:8][CH:7]([N:15]([CH3:17])[CH3:16])[CH2:6][C:5]3=2)=[O:25])[CH:20]=1Komponenten
3
Versuchsvorschrift
Beginning with 8.7 mg (0.038 mMol) 6-amino-3-(dimethyl)amino-1,2,3,4-tetrahydro-9H-carbazole and 10.0 mg (0.090 mMol) 5-methylfuran-3-carboxylic acid, 7.9 mg (62%) of the title compound were recovered as a beige solid.
Quellen und Nachweise
- ORD-Eintrag
- ord-9cf09a4ca21e4d13842c462d6cef3a6c
- Quelldatensatz
- uspto-grants-2002_04