1-Hexadecylthio-3-trityloxy-2-propanol → 1-Hexadecylthio-3-(3-iodopropylsulfonylamino)-2-methylcarbamoyloxypropane
Reaktionsgleichung
ClCCCCS(NCC(OC)C[O:13][C:14](=O)[NH:15][CH2:16]CCCCCCCCCCCCCCCCC)(=O)=O.[CH2:37]([S:53][CH2:54][CH:55]([OH:77])[CH2:56]OC(C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1)[CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH2:43][CH2:44][CH2:45][CH2:46][CH2:47][CH2:48][CH2:49][CH2:50][CH2:51][CH3:52].C(SCC(OC)C[NH:98][S:99]([CH2:102][CH2:103][CH2:104][I:105])(=[O:101])=[O:100])CCCCCCCCCCCCCCC>>[CH2:37]([S:53][CH2:54][CH:55]([O:77][C:14](=[O:13])[NH:15][CH3:16])[CH2:56][NH:98][S:99]([CH2:102][CH2:103][CH2:104][I:105])(=[O:100])=[O:101])[CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH2:43][CH2:44][CH2:45][CH2:46][CH2:47][CH2:48][CH2:49][CH2:50][CH2:51][CH3:52]Komponenten
4
Edukt 3
Produkt 1
Versuchsvorschrift
3-(3-Chloropropylsulfonylamino)-1-hexadecylthio-2-methylcarbamoyloxypropan III c1 is allowed to react and worked up by the same procedure as described in (5). The summary of the experimental condition and the physical data of the product are listed in the Table 8.