HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
tert-Butyl 2-bromo-2-methylpropionate → 2-(2-t-Butoxycarbonylprop-2-yloxyimino)-2-(thien-2-yl)acetic acid
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | tert-Butyl 2-bromo-2-methylpropionate | HCID 90290 | — |
| Edukt | Benethamine(1+) | HCID 1549262 | — |
| Edukt | 2-Hydroxyimino(thien-2-yl)acetic acid | HCID 73629644 | — |
| Lösungsmittel | Ethanol | HCID 702 | — |
| Produkt | 2-(2-t-Butoxycarbonylprop-2-yloxyimino)-2-(thien-2-yl)acetic acid | HCID 54300039 | 78% |
Reaktionsschritte
The title compound was prepared from 2-hydroxyimino-2-(thien-2-yl)acetic acid (syn isomer) and t-butyl 2-bromo-2-methylpropionate, in a similar manner to that described for Preparation 5, in 78% yield as a colourless oil, and was characterised as the N-benzyl-2-phenylethylammonium salt, m.p. 201.3°-201.9° (from ethanol).
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US04103084 |
| Quelldatensatz | uspto-grants-1978_07 |
| ORD ID | ord-e88a5d35eb724d209c97cfd351079013 |
| Quellennotiz | uspto-grants-1978_07 |